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- W2084875119 abstract "The synthesis and characterization of the perchlorato derivatives of bis(isocyanide)tetrakis(phenyl)porphynatoruthenium(III) [Ru(TPP)(RNC)2]ClO4 (1, R=tBu; 2, R=2,6-xylyl) are reported. The 1H-NMR isotropic shifts at 298 K of the pyrrole protons of the two complexes, varied from −5.44 ppm for 1 to +2.55 ppm for 2 rather than the expected −31 ppm, based on previously studied aryl complexes of low-spin ruthenium porphyrins. The EPR spectrum of 2 in solution is axial, with g⊥=2.07 and gII=1.99 at 4 K, Σg2=12.53. These spectroscopic observations are indicative of a metal-based electron for complex with a (dxz, dyz)4 (dxy)1 ground state at any temperature." @default.
- W2084875119 created "2016-06-24" @default.
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- W2084875119 date "2001-06-01" @default.
- W2084875119 modified "2023-09-25" @default.
- W2084875119 title "1H-NMR and EPR studies of the electronic structure of low-spin ruthenium(III) isocyanide porphyrin complexes: unusual (dxz,dyz)4 (dxy)1 configuration" @default.
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- W2084875119 doi "https://doi.org/10.1016/s0022-328x(01)00830-0" @default.
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