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- W2084876328 abstract "Numerical calculation has been undertaken on the temperature dependence of photoluminescence (PL) intensity and PL lifetime of fac tris(2-phenylpyridine) iridium $[mathrm{Ir}{(mathrm{ppy})}_{3}]$ phosphorescent material doped in $4,{4}^{ensuremath{'}}$-bis[N-(p-tolyl)-N-phenyl-amino]biphenyl (TPD) and compared with the experimental result. We use a model in which three zero-field splitting substates 1, 2, and 3 of the lowest-energy metal-to-ligand--charge-transfer triplet states are responsible for the phosphorescence, together with the lowest-energy triplet state of TPD (level 4) at $645phantom{rule{0.3em}{0ex}}{mathrm{cm}}^{ensuremath{-}1}$ below the lowest triplet substate 1 of $mathrm{Ir}{(mathrm{ppy})}_{3}$. We assume the nonradiative one-phonon relaxation is undertaken among these four levels. A good agreement is obtained between the temperature dependence of the observed and calculated PL intensities and lifetimes." @default.
- W2084876328 created "2016-06-24" @default.
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- W2084876328 date "2005-09-12" @default.
- W2084876328 modified "2023-10-16" @default.
- W2084876328 title "Temperature dependence of phosphorescence intensity and lifetime of tris(2-phenylpyridine) iridium doped in the fluorescent material TDP" @default.
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- W2084876328 doi "https://doi.org/10.1103/physrevb.72.125109" @default.
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