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- W2084927076 abstract "Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in a simple thermodynamic system with temperature-independent constant-volume heat capacity, C, is TC/k. A physical interpretation of this function is given for three such systems: an ideal monatomic gas, an ideal gas of diatomic molecules with rotational motion and a solid in the Dulong–Petit limit of high temperature. T1/2 emerges as a natural measure of the number of accessible states for a single particle in one dimension. Extension to N particles in three dimensions leads to TC/k as the total number of possible arrangements or microstates. The different microstates of the system are thus shown a posteriori to be equally probable, with probability T−C/k, which implies that for the purposes of counting states the particles are distinguishable. The most probable energy state of the system is determined by the degeneracy of the microstates." @default.
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- W2084927076 date "2007-12-17" @default.
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- W2084927076 title "Thermodynamic entropy and the accessible states of some simple systems" @default.
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- W2084927076 doi "https://doi.org/10.1088/0143-0807/29/1/013" @default.
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