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- W2084960438 abstract "Extraction of vanadium(V) with 8-quinolinol into chlorobenzene is discussed. Three dimeric species are shown to be responsible for the extraction: 2VO3- + 4(HOx)o α (V2O3Ox4)o + 2OH-; log Kex,1 = -1.60 ± 0.10 2VO3- + 4(HOx)o + H+ + ClO4- α (V2O3H(Ox)4 · ClO4)o + 2OH-; log Kex,2 = 1.55 ± 0.10 2VO3- + 4(HOx)o + 2H+ + 2ClO4- α (V2O2Ox4 · 2ClO4)o + 2OH-; log Kex,3 = 2.65 ± 0.10 The vanadium(V) complex of 8-quinolinol has also been studied by thermogravimetry and i.r. and visible spectroscopy; an oxo-bridged dimeric structure is postulated. In contrast to 8-quinolinol, 2-methyl-8-quinolinol gives a monomeric vanadium(V) complex under the usual experimental conditions." @default.
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- W2084960438 date "1980-03-01" @default.
- W2084960438 modified "2023-09-25" @default.
- W2084960438 title "Vanadium(V) 8-quinolinolate—monomer or dimer?" @default.
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- W2084960438 doi "https://doi.org/10.1016/s0003-2670(01)93169-1" @default.
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