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- W2085005457 abstract "Abstract Treatment of an acetonitrile solution of CuCN with methylcycloarsoxane (CH 3 AsO) n at 110 °C affords the coordination polymer [CuCN{ cyclo ‐(CH 3 AsO) 4 }] ( 1 ), in which infinite CuCN zigzag chains are linked by μ‐As 1 , As 3 cyclotetramers (CH 3 AsO) 4 into an open 3‐D framework. Under similar solvothermal conditions, reaction of CuSCN with (CH 3 AsO) n in the presence of KSCN leads to metal‐mediated ring expansion of the cyclo‐arsoxane to yield the complex [{K[ cyclo ‐(CH 3 AsO) 5 ] 2 }Cu(NCS) 2 ] ( 2 ). This contains discrete [Cu(NCS‐κ N ) 2 { cyclo ‐(CH 3 AsO) 5 κ As } 2 ] — anions that bridge κ 10 O coordinated potassium cations into infinite chains. In contrast, the structure directing role of the [K(1, 7DT18C6) 2 ] + sandwich building units for the solvothermal product [{K(1, 7DT18C6) 2 }Cu 6 (CN) 7 ] ( 3 ) (1, 7DT18C6 = 1, 7‐dithia‐18‐crown‐6) leads to formation of an open [{Cu 6 (CN) 7 } — ] framework. Individual [K(1, 7DT18C6) 2 ] + moieties bridge Cu Atoms in a μ‐ S 1 , S 7 mode and are encapsulated within the large [Cu 26 (CN) 28 ] 2— cages of the cyanocuprate(I) network." @default.
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- W2085005457 date "2005-02-21" @default.
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- W2085005457 title "Copper(I) Pseudohalide Coordination Polymers containing Macrocyclic Methylcycloarsoxane (CH3AsO)n (n = 4, 5) or 1, 7-Dithia-18-crown-6 Bridging UnitsKupfer(I)-Pseudohalogenid-haltige Koordinationspolymere mit den Makrozyklen Methylcycloarsoxan (CH3AsO)n (n = 4, 5) oder 1, 7-Dithia-18-Krone-6 als Br�ckenliganden" @default.
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- W2085005457 doi "https://doi.org/10.1002/zaac.200400426" @default.
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