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- W2085024449 abstract "A light-driven pseudo[4]rotaxane 1, based on α-cyclodextrin (α-CyD) and cucurbit[7]uril (CB[7]), is prepared in an easy and convenient manner. The reference pseudo[2]rotaxane 2 and pseudo[3]rotaxane 2′ are obtained via the insertion of α-CyD and CB[7] onto the dumbbell 3, thus including an azobenzene unit and two viologen moieties, respectively. The CyD macrocycle in pseudo[4]rotaxane 1 can be photochemically stimulated to shuttle accompanied with obvious induced circular dichroism (ICD) signals. The ICD performances of these pseudorotaxanes, including ICD in aqueous solution, variable-temperature ICD, ICD in confected hydrogel systems and in solid-state films, are investigated for their conformational identification. The photo-driven shuttling of the CyD macrocycle in pseudo[4]rotaxane 1 is easier than in the CyD-based pseudo[2]rotaxane 2, especially in non-solution media. This can be attributed to the space exploitation of CB[7]-included parts, which aid the movement of α-CyD." @default.
- W2085024449 created "2016-06-24" @default.
- W2085024449 creator A5013468377 @default.
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- W2085024449 creator A5067366815 @default.
- W2085024449 creator A5068998523 @default.
- W2085024449 date "2007-03-23" @default.
- W2085024449 modified "2023-09-25" @default.
- W2085024449 title "A Light-Driven Pseudo[4]rotaxane Encoded by Induced Circular Dichroism in a Hydrogel" @default.
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- W2085024449 doi "https://doi.org/10.1002/adfm.200600981" @default.
- W2085024449 hasPublicationYear "2007" @default.
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