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- W2085024488 abstract "A high-resolution Fourier transform infrared spectrum of the second stretching overtone band system of monoisotopic stannane, 116SnH4, has been measured and rotationally analyzed in detail up to J′ = 17. The rotational levels of the close-lying A1 and F2 vibrational states have been treated simultaneously by including vibration—rotation coupling terms in the Hamiltonian. The A1/F2 vibrational energy level separation has been found to be 0.026(2) cm−1 with the A1 state being higher in energy. 449 infrared transitions were used as data in optimizing 12 upper state parameters, and the standard deviation of the fit obtained is 0.0023 cm−1. The results are discussed in terms of vibrational localization." @default.
- W2085024488 created "2016-06-24" @default.
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- W2085024488 date "1993-04-01" @default.
- W2085024488 modified "2023-09-23" @default.
- W2085024488 title "The second stretching overtone band system of 116 SnH4 at 5539 cm−1: how close to the local mode limit?" @default.
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- W2085024488 doi "https://doi.org/10.1016/0009-2614(93)87137-r" @default.
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