FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085051272> ?p ?o ?g. }

• W2085051272 endingPage "2457" @default.
• W2085051272 startingPage "2452" @default.
• W2085051272 abstract "The electrochemical and spectral properties of some copper(I) polypyridyl complexes based on 6,7-dihydrodibenzo[b,j][1,10]phenanthroline, dmbiq, and 6,7-dihydrodipyrido[2,3-b:3',2'-j][1,10]phenanthroline, dmbinap, are reported. These complexes are [Cu(dmbiq)(2)](+), 1; [Cu(dmbiq)(PPh(3))(2)](+), 2; [Cu(dmbinap)(2)](+), 3; and [Cu(dmbinap)(PPh(3))(2)](+), 4. 3 and 4 may be reduced to form ligand-based radical anion species. The resonance Raman spectra of 3(*)()(-)() and 4(*)()(-)() are almost identical and correspond closely to the spectrum of dmbinap(*)()(-)() and the reported spectra of complexes containing 2,2'-biquinoline radical anion moieties. Reduction processes for 1 and 2 are irreversible. For 1 the electronic spectral changes arising from reduction suggest demetallation of the complex. The structure of [Cu(C(18)H(12)N(4))(2)][BF(4)].CH(2)Cl(2) (3[BF(4)].CH(2)Cl(2)) was determined by single-crystal X-ray diffraction. It crystallized in the monoclinic space group P2(1)/c with cell dimensions a = 14.059(7) Å, b = 15.058(6) Å, c = 16.834(9) Å, beta = 111.56(5) degrees, Z = 4, rho(calcd) = 1.611 g/cm(3), and R(F(o)) = 0.0497." @default.
• W2085051272 created "2016-06-24" @default.
• W2085051272 creator A5011728534 @default.
• W2085051272 creator A5014892675 @default.
• W2085051272 creator A5040882914 @default.
• W2085051272 date "1996-01-01" @default.
• W2085051272 modified "2023-10-17" @default.
• W2085051272 title "Spectroelectrochemical Studies of Copper(I) Complexes with Binaphthyridine and Biquinoline Ligands. Crystal Structure Determination of Bis(6,7-dihydrodipyrido[2,3-<i>b</i>:3‘,2‘-<i>j</i>][1,10]phenanthroline)copper(I) Tetrafluoroborate" @default.
• W2085051272 cites W1969919479 @default.
• W2085051272 cites W1980905899 @default.
• W2085051272 cites W1982127732 @default.
• W2085051272 cites W1987789400 @default.
• W2085051272 cites W1997181021 @default.
• W2085051272 cites W1998271866 @default.
• W2085051272 cites W1998644325 @default.
• W2085051272 cites W2004977643 @default.
• W2085051272 cites W2006093198 @default.
• W2085051272 cites W2016029348 @default.
• W2085051272 cites W2018073814 @default.
• W2085051272 cites W2022904136 @default.
• W2085051272 cites W2028164312 @default.
• W2085051272 cites W2029284071 @default.
• W2085051272 cites W2038739185 @default.
• W2085051272 cites W2041295630 @default.
• W2085051272 cites W2045905945 @default.
• W2085051272 cites W2066728845 @default.
• W2085051272 cites W2067450682 @default.
• W2085051272 cites W2077008405 @default.
• W2085051272 cites W2245244670 @default.
• W2085051272 cites W2320675543 @default.
• W2085051272 cites W2343648211 @default.
• W2085051272 cites W2950757183 @default.
• W2085051272 cites W3138749256 @default.
• W2085051272 doi "https://doi.org/10.1021/ic951217a" @default.
• W2085051272 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11666456" @default.
• W2085051272 hasPublicationYear "1996" @default.
• W2085051272 type Work @default.
• W2085051272 sameAs 2085051272 @default.
• W2085051272 citedByCount "29" @default.
• W2085051272 countsByYear W20850512722013 @default.
• W2085051272 countsByYear W20850512722016 @default.
• W2085051272 countsByYear W20850512722017 @default.
• W2085051272 countsByYear W20850512722020 @default.
• W2085051272 crossrefType "journal-article" @default.
• W2085051272 hasAuthorship W2085051272A5011728534 @default.
• W2085051272 hasAuthorship W2085051272A5014892675 @default.
• W2085051272 hasAuthorship W2085051272A5040882914 @default.
• W2085051272 hasConcept C109214941 @default.
• W2085051272 hasConcept C115624301 @default.
• W2085051272 hasConcept C116569031 @default.
• W2085051272 hasConcept C120665830 @default.
• W2085051272 hasConcept C121332964 @default.
• W2085051272 hasConcept C139210041 @default.
• W2085051272 hasConcept C145148216 @default.
• W2085051272 hasConcept C147789679 @default.
• W2085051272 hasConcept C170493617 @default.
• W2085051272 hasConcept C17525397 @default.
• W2085051272 hasConcept C178790620 @default.
• W2085051272 hasConcept C185592680 @default.
• W2085051272 hasConcept C2777660389 @default.
• W2085051272 hasConcept C40003534 @default.
• W2085051272 hasConcept C52859227 @default.
• W2085051272 hasConcept C544778455 @default.
• W2085051272 hasConcept C55493867 @default.
• W2085051272 hasConcept C61276311 @default.
• W2085051272 hasConcept C71240020 @default.
• W2085051272 hasConcept C73922627 @default.
• W2085051272 hasConcept C8010536 @default.
• W2085051272 hasConceptScore W2085051272C109214941 @default.
• W2085051272 hasConceptScore W2085051272C115624301 @default.
• W2085051272 hasConceptScore W2085051272C116569031 @default.
• W2085051272 hasConceptScore W2085051272C120665830 @default.
• W2085051272 hasConceptScore W2085051272C121332964 @default.
• W2085051272 hasConceptScore W2085051272C139210041 @default.
• W2085051272 hasConceptScore W2085051272C145148216 @default.
• W2085051272 hasConceptScore W2085051272C147789679 @default.
• W2085051272 hasConceptScore W2085051272C170493617 @default.
• W2085051272 hasConceptScore W2085051272C17525397 @default.
• W2085051272 hasConceptScore W2085051272C178790620 @default.
• W2085051272 hasConceptScore W2085051272C185592680 @default.
• W2085051272 hasConceptScore W2085051272C2777660389 @default.
• W2085051272 hasConceptScore W2085051272C40003534 @default.
• W2085051272 hasConceptScore W2085051272C52859227 @default.
• W2085051272 hasConceptScore W2085051272C544778455 @default.
• W2085051272 hasConceptScore W2085051272C55493867 @default.
• W2085051272 hasConceptScore W2085051272C61276311 @default.
• W2085051272 hasConceptScore W2085051272C71240020 @default.
• W2085051272 hasConceptScore W2085051272C73922627 @default.
• W2085051272 hasConceptScore W2085051272C8010536 @default.
• W2085051272 hasIssue "9" @default.
• W2085051272 hasLocation W20850512721 @default.
• W2085051272 hasLocation W20850512722 @default.
• W2085051272 hasOpenAccess W2085051272 @default.
• W2085051272 hasPrimaryLocation W20850512721 @default.
• W2085051272 hasRelatedWork W1964159414 @default.
• W2085051272 hasRelatedWork W1964369749 @default.
• W2085051272 hasRelatedWork W1981634121 @default.
• W2085051272 hasRelatedWork W2078454166 @default.

• next