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• W2085053342 abstract "The adsorption kinetics of heptanethiol [CH3(CH2)6SH] on Cu(110) and the ordering of monolayer films prepared by ultrahigh vacuum vapor deposition have been studied by means of thermal-desorption spectroscopy, X-ray photoelectron spectroscopy, low-energy electron diffraction, and scanning tunneling microscopy. Below 200 K, heptanethiol is found to grow in multilayers for which a molecular binding energy of 63 kJ/mol was determined. The formation of the chemisorbed monolayer takes place via a physisorbed precursor. Heating the chemisorbed layer leads to a dissociative desorption of the alkyl chain with an enthalpy of 117 kJ/mol. In contrast to the rather disordered physisorbed overlayers, several superstructures for the various coverages have been observed for the chemisorbed phase. Heating the saturated monolayer to 350 K results in a well-ordered ( ) structure." @default.
• W2085053342 created "2016-06-24" @default.
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• W2085053342 date "1999-04-28" @default.
• W2085053342 modified "2023-09-27" @default.
• W2085053342 title "Adsorption of Heptanethiol on Cu(110)" @default.
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• W2085053342 doi "https://doi.org/10.1021/la981510y" @default.
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