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- W2085055257 abstract "A series of ten N-alkyl(aralkyl)-2-phenyl-3-cyanoaziridines has been synthesized to continue investigations of the molecular stereochemistry and bonding of functionalized aziridines. Substantial spectroscopic evidence is presented which indicates the presence of stereoselective hyperconjugation between the phenyl and nitrile groups and the aziridine ring. The 1H and 13C nmr chemical shifts are rationalized in terms of the interactions of the substituents on the aziridine ring, and how these interactions vary with the steric bulk of the nitrogen substituents. Various stereoselective coupling constants (1H-1H and 13C-1H) are also reported." @default.
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- W2085055257 date "1988-03-01" @default.
- W2085055257 modified "2023-09-27" @default.
- W2085055257 title "Stereochemistry and bonding inN-substituted-2-phenyl-3-cyanoaziridines" @default.
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- W2085055257 doi "https://doi.org/10.1002/jhet.5570250201" @default.
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