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• W2085068036 endingPage "116" @default.
• W2085068036 startingPage "79" @default.
• W2085068036 abstract "This paper discusses synthetic strategies for fabrication of new organized planar inorganic, polymeric, composite and bio-inorganic nanostructures by methods based on chemical reactions and physical interactions at the gas–liquid interface, Langmuir monolayer technique, interfacial ligand exchange and substitution reactions, self-assembling and self-organization processes, DNA templating and scaffolding. Stable reproducible planar assemblies of ligand-stabilized molecular nanoclusters containing definite number of atoms have been formed on solid substrate surfaces via preparation and deposition of mixed Langmuir monolayers composed by nanocluster and surfactant molecules. A novel approach to synthesis of inorganic nanoparticles and to formation of self-organized planar inorganic nanostructures has been introduced. In that approach, nanoparticles and nanostructures are fabricated via decomposition of insoluble metal-organic precursor compounds in a layer at the gas–liquid interface. The ultimately thin and anisotropic dynamic monomolecular reaction system was realized in that approach with quasi-two-dimensional growth and organization of nanoparticles and nanostructures in the plain of Langmuir monolayer. Photochemical and redox reactions were used to initiate processes of interfacial nucleation and growth of inorganic phase. It has been demonstrated that morphology of resulting inorganic nanostructures can be controlled efficiently by variations of growth conditions via changes in state and composition of interfacial planar reaction media, and by variations of composition of adjacent bulk phases. Planar arrays and chains of iron oxide and ultrasmall noble metal (Au and Pd) nanoparticles, nanowires and new organized planar disk, ring, net-like, labyrinth and very high-surface area nanostructures were obtained by methods based on that approach. Highly organized monomolecular polymeric films on solid substrates were obtained via deposition of Langmuir monolayer formed by water-insoluble amphiphilic polycation molecules. Corresponding nanoscale-ordered planar polymeric nanocomposite films with incorporated ligand-stabilized molecular metallic nanoclusters and interfacially grown nanoparticles were fabricated successfully. Novel planar DNA complexes with amphiphilic polycation monolayer were formed at the gas–aqueous phase interface and then deposited on solid substrates. Toroidal and new net-like conformations were discovered in those complexes. Nanoscale supramolecular organization of the complexes was dependent on cationic amphiphile monolayer state during the DNA binding. These monolayer and multilayer DNA/amphiphilic polycation complex Langmuir–Blodgett films were used as templates and nanoreactors for generation of inorganic nanostructures via metal cation binding with DNA and following inorganic phase growth reactions. As a result, ultrathin polymeric nanocomposite films with integrated DNA building blocks and organized inorganic semiconductor (CdS) and iron oxide quasi-linear nanostructures were formed. It has been demonstrated that interaction of deposited planar DNA/amphiphilic polycation complexes with bulk phase colloid inorganic cationic ligands (CdSe nano-rods) can result in formation of new highly organized hybrid bio-inorganic nanostructures via interfacial ligand exchange and self-organization processes. The methods developed can be useful for investigation of fundamental mechanisms of nanoscale structural organization and transformation processes in various inorganic and molecular systems including bio-molecular and bio-inorganic nanostructures. Also, those methods are relatively simple, environmentally safe and thus could prove to be efficient practical instruments of molecular nanotechnology with potential of design and cost-effective fabrication of new controlled-morphology organized planar inorganic and composite nanostructured materials. Possible applications of obtained nanostructures and future developments are also discussed." @default.
• W2085068036 created "2016-06-24" @default.
• W2085068036 creator A5021699374 @default.
• W2085068036 date "2004-11-01" @default.
• W2085068036 modified "2023-10-14" @default.
• W2085068036 title "Interfacially formed organized planar inorganic, polymeric and composite nanostructures" @default.
• W2085068036 cites W1511331555 @default.
• W2085068036 cites W1511485411 @default.
• W2085068036 cites W1513209253 @default.
• W2085068036 cites W16525915 @default.
• W2085068036 cites W1658532712 @default.
• W2085068036 cites W1856850207 @default.
• W2085068036 cites W1863291135 @default.
• W2085068036 cites W1964377594 @default.
• W2085068036 cites W1964555133 @default.
• W2085068036 cites W1964574260 @default.
• W2085068036 cites W1964933396 @default.
• W2085068036 cites W1965200760 @default.
• W2085068036 cites W1965332421 @default.
• W2085068036 cites W1965657616 @default.
• W2085068036 cites W1966387471 @default.
• W2085068036 cites W1967019995 @default.
• W2085068036 cites W1967079896 @default.
• W2085068036 cites W1967092620 @default.
• W2085068036 cites W1967398255 @default.
• W2085068036 cites W1967503251 @default.
• W2085068036 cites W1968010460 @default.
• W2085068036 cites W1968044889 @default.
• W2085068036 cites W1968083459 @default.
• W2085068036 cites W1968398679 @default.
• W2085068036 cites W1969457873 @default.
• W2085068036 cites W1969535658 @default.
• W2085068036 cites W1970666225 @default.
• W2085068036 cites W1970826183 @default.
• W2085068036 cites W1973457343 @default.
• W2085068036 cites W1973663328 @default.
• W2085068036 cites W1974945275 @default.
• W2085068036 cites W1975350414 @default.
• W2085068036 cites W1975518034 @default.
• W2085068036 cites W1975908426 @default.
• W2085068036 cites W1976626713 @default.
• W2085068036 cites W1978024845 @default.
• W2085068036 cites W1978227600 @default.
• W2085068036 cites W1978466539 @default.
• W2085068036 cites W1978822626 @default.
• W2085068036 cites W1979884986 @default.
• W2085068036 cites W1980256024 @default.
• W2085068036 cites W1980374305 @default.
• W2085068036 cites W1980461977 @default.
• W2085068036 cites W1980469522 @default.
• W2085068036 cites W1981054514 @default.
• W2085068036 cites W1982584071 @default.
• W2085068036 cites W1983224532 @default.
• W2085068036 cites W1983382833 @default.
• W2085068036 cites W1983554118 @default.
• W2085068036 cites W1983630781 @default.
• W2085068036 cites W1983906337 @default.
• W2085068036 cites W1984355970 @default.
• W2085068036 cites W1985333274 @default.
• W2085068036 cites W1985411541 @default.
• W2085068036 cites W1986070652 @default.
• W2085068036 cites W1986115874 @default.
• W2085068036 cites W1986165362 @default.
• W2085068036 cites W1986632514 @default.
• W2085068036 cites W1986681408 @default.
• W2085068036 cites W1987029065 @default.
• W2085068036 cites W1989054909 @default.
• W2085068036 cites W1989077120 @default.
• W2085068036 cites W1989231375 @default.
• W2085068036 cites W1989882632 @default.
• W2085068036 cites W1990304289 @default.
• W2085068036 cites W1990433875 @default.
• W2085068036 cites W1991846896 @default.
• W2085068036 cites W1992361253 @default.
• W2085068036 cites W1992937639 @default.
• W2085068036 cites W1993576170 @default.
• W2085068036 cites W1994336730 @default.
• W2085068036 cites W1994619139 @default.
• W2085068036 cites W1996252455 @default.
• W2085068036 cites W1996764433 @default.
• W2085068036 cites W1997599957 @default.
• W2085068036 cites W1998420645 @default.
• W2085068036 cites W1999156526 @default.
• W2085068036 cites W2000767457 @default.
• W2085068036 cites W2001127780 @default.
• W2085068036 cites W2001809903 @default.
• W2085068036 cites W2002413235 @default.
• W2085068036 cites W2003118313 @default.
• W2085068036 cites W2003333956 @default.
• W2085068036 cites W2004322997 @default.
• W2085068036 cites W2004425470 @default.
• W2085068036 cites W2004550441 @default.
• W2085068036 cites W2004824520 @default.
• W2085068036 cites W2004828591 @default.
• W2085068036 cites W2005022133 @default.
• W2085068036 cites W2005062196 @default.
• W2085068036 cites W2005403117 @default.
• W2085068036 cites W2007820897 @default.

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