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- W2085086087 abstract "A new access to 11β-(alkynyl)estranes I is described. The synthesis of key intermediate 11β-ethynylestr-4-ene-3,17-dione 8 can be achieved by stereoselective thermodynamically controlled formation of 11β-aldehyde 1, its conversion to vinyl bromide 7 by Wittig reaction and subsequent dehydrobromination. Broad variation of the acetylenic 11β-substitution is possible by nucleophilic substitution as well as transition metal mediated coupling reactions." @default.
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- W2085086087 date "1993-08-01" @default.
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- W2085086087 title "Synthesis of 11β-(alkynyl)substituted 19-norsteroids" @default.
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- W2085086087 doi "https://doi.org/10.1016/s0040-4039(00)73966-9" @default.
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