FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085102764> ?p ?o ?g. }

• W2085102764 endingPage "18" @default.
• W2085102764 startingPage "1" @default.
• W2085102764 abstract "The unimolecular decomposition reaction of dimethyl ether (DME) was studied theoretically using RRKM/master equation calculations. The calculated decomposition rate is significantly different from that utilized in prior work (Fischer et al., Int J Chem Kinet 2000, 32, 713–740; Curran et al., Int J Chem Kinet 2000, 32, 741–759). DME pyrolysis experiments were performed at 980 K in a variable-pressure flow reactor at a pressure of 10 atm, a considerably higher pressure than previous validation data. Both unimolecular decomposition and radical abstraction are significant in describing DME pyrolysis, and hierarchical methodology was applied to produce a comprehensive high-temperature model for pyrolysis and oxidation that includes the new decomposition parameters and more recent small molecule/radical kinetic and thermochemical data. The high-temperature model shows improved agreement against the new pyrolysis data and the wide range of high-temperature oxidation data modeled in prior work, as well as new low-pressure burner-stabilized species profiles (Cool et al., Proc Combust Inst 2007, 31, 285–294) and laminar flame data for DME/methane mixtures (Chen et al., Proc Combust Inst 2007, 31, 1215–1222). The high-temperature model was combined with low-temperature oxidation chemistry (adopted from Fischer et al., Int J Chem Kinet 2000, 32, 713–740), with some modifications to several important reactions. The revised construct shows good agreement against high- as well as low-temperature flow reactor and jet-stirred reactor data, shock tube ignition delays, and laminar flame species as well as flame speed measurements. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 40: 1–18, 2008" @default.
• W2085102764 created "2016-06-24" @default.
• W2085102764 creator A5011528259 @default.
• W2085102764 creator A5016915822 @default.
• W2085102764 creator A5022742649 @default.
• W2085102764 creator A5045809201 @default.
• W2085102764 date "2008-01-01" @default.
• W2085102764 modified "2023-10-05" @default.
• W2085102764 title "Thermal decomposition reaction and a comprehensive kinetic model of dimethyl ether" @default.
• W2085102764 cites W1969455831 @default.
• W2085102764 cites W1971383747 @default.
• W2085102764 cites W1972159084 @default.
• W2085102764 cites W1972247240 @default.
• W2085102764 cites W1973800929 @default.
• W2085102764 cites W1980362792 @default.
• W2085102764 cites W1982856662 @default.
• W2085102764 cites W1986355909 @default.
• W2085102764 cites W1990819691 @default.
• W2085102764 cites W1990891510 @default.
• W2085102764 cites W1994268533 @default.
• W2085102764 cites W1994582737 @default.
• W2085102764 cites W1996415621 @default.
• W2085102764 cites W2003460328 @default.
• W2085102764 cites W2004279543 @default.
• W2085102764 cites W2008367764 @default.
• W2085102764 cites W2011218289 @default.
• W2085102764 cites W2012488271 @default.
• W2085102764 cites W2014276813 @default.
• W2085102764 cites W2014761764 @default.
• W2085102764 cites W2018043796 @default.
• W2085102764 cites W2018657505 @default.
• W2085102764 cites W2022333924 @default.
• W2085102764 cites W2023271753 @default.
• W2085102764 cites W2023344034 @default.
• W2085102764 cites W2024552682 @default.
• W2085102764 cites W2026375492 @default.
• W2085102764 cites W2031525325 @default.
• W2085102764 cites W2035596398 @default.
• W2085102764 cites W2041449670 @default.
• W2085102764 cites W2042019106 @default.
• W2085102764 cites W2043244766 @default.
• W2085102764 cites W2051554285 @default.
• W2085102764 cites W2056118873 @default.
• W2085102764 cites W2058179787 @default.
• W2085102764 cites W2074981215 @default.
• W2085102764 cites W2075730114 @default.
• W2085102764 cites W2077296184 @default.
• W2085102764 cites W2078479834 @default.
• W2085102764 cites W2081110399 @default.
• W2085102764 cites W2086957099 @default.
• W2085102764 cites W2087799348 @default.
• W2085102764 cites W2092925040 @default.
• W2085102764 cites W2093173078 @default.
• W2085102764 cites W2095154719 @default.
• W2085102764 cites W2121913031 @default.
• W2085102764 cites W2142408141 @default.
• W2085102764 cites W2143981217 @default.
• W2085102764 cites W2148284063 @default.
• W2085102764 cites W2152069856 @default.
• W2085102764 cites W2163746642 @default.
• W2085102764 cites W2328842435 @default.
• W2085102764 cites W2334976435 @default.
• W2085102764 cites W2949648819 @default.
• W2085102764 cites W343090255 @default.
• W2085102764 doi "https://doi.org/10.1002/kin.20285" @default.
• W2085102764 hasPublicationYear "2008" @default.
• W2085102764 type Work @default.
• W2085102764 sameAs 2085102764 @default.
• W2085102764 citedByCount "416" @default.
• W2085102764 countsByYear W20851027642012 @default.
• W2085102764 countsByYear W20851027642013 @default.
• W2085102764 countsByYear W20851027642014 @default.
• W2085102764 countsByYear W20851027642015 @default.
• W2085102764 countsByYear W20851027642016 @default.
• W2085102764 countsByYear W20851027642017 @default.
• W2085102764 countsByYear W20851027642018 @default.
• W2085102764 countsByYear W20851027642019 @default.
• W2085102764 countsByYear W20851027642020 @default.
• W2085102764 countsByYear W20851027642021 @default.
• W2085102764 countsByYear W20851027642022 @default.
• W2085102764 countsByYear W20851027642023 @default.
• W2085102764 crossrefType "journal-article" @default.
• W2085102764 hasAuthorship W2085102764A5011528259 @default.
• W2085102764 hasAuthorship W2085102764A5016915822 @default.
• W2085102764 hasAuthorship W2085102764A5022742649 @default.
• W2085102764 hasAuthorship W2085102764A5045809201 @default.
• W2085102764 hasConcept C121332964 @default.
• W2085102764 hasConcept C124681953 @default.
• W2085102764 hasConcept C135889238 @default.
• W2085102764 hasConcept C147597530 @default.
• W2085102764 hasConcept C160434732 @default.
• W2085102764 hasConcept C161790260 @default.
• W2085102764 hasConcept C178790620 @default.
• W2085102764 hasConcept C185592680 @default.
• W2085102764 hasConcept C2779300417 @default.
• W2085102764 hasConcept C2780407432 @default.
• W2085102764 hasConcept C36759035 @default.
• W2085102764 hasConcept C62520636 @default.

• next