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- W2085103363 endingPage "499" @default.
- W2085103363 startingPage "489" @default.
- W2085103363 abstract "We have recently developed a novel type of gel called the slide-ring gel or topological gel that is different from physical and chemical gels by using the supramolecular architecture with topological characteristics. In this gel, polymer chains with bulky end groups exhibit neither covalently cross-links as in chemical gels nor attractive interactions as in physical gels but are topologically interlocked by figure-of-eight cross-links. Hence, these cross-links can pass along the polymer chains freely to equalize the tension of the threading polymer chains similarly to pulleys; this is called the pulley effect. The slide-ring gel is a new cross-linking concept for the polymer network as well as a real example of a slip-link model or sliding gel, which was previously considered only theoretically. In this study, we review the synthesis, structure, and mechanical properties of the slide-ring gels with freely movable cross-linking junctions based primarily on our recent studies. The pulley effect of the slide-ring gels has been recently confirmed by mechanical measurements, small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), quasi-elastic light scattering (QELS), etc. This concept can be applied to not only gels but also to a wide variety of polymeric materials without solvents." @default.
- W2085103363 created "2016-06-24" @default.
- W2085103363 creator A5047584172 @default.
- W2085103363 date "2007-05-09" @default.
- W2085103363 modified "2023-10-17" @default.
- W2085103363 title "Novel Cross-Linking Concept of Polymer Network: Synthesis, Structure, and Properties of Slide-Ring Gels with Freely Movable Junctions" @default.
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- W2085103363 doi "https://doi.org/10.1295/polymj.pj2006239" @default.
- W2085103363 hasPublicationYear "2007" @default.
- W2085103363 type Work @default.