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- W2085103421 abstract "The IR laser photochemistry of mixtures of silane and deuterium was investigated from room temperature to 500 K. Deuterated monosilanes, disilanes, H2 and HD and trace amounts of trisilane were found as gas-phase products. The competitive insertion of silylene into D2 and SiH4 was investigated and a relative insertion rate constant of 0.36 for insertion into deuterium relative to silane was obtained. The temperature dependence for these processes was also examined and showed that they exhibited essentially equal activation energies." @default.
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- W2085103421 date "1990-04-01" @default.
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- W2085103421 title "The IR laser photochemistry of monosilane-deuterium mixtures" @default.
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- W2085103421 doi "https://doi.org/10.1016/1010-6030(90)87065-j" @default.
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