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- W2085106867 abstract "High-resolution proton magnetic resonance spectra of the C-terminal half-molecule of ovotransferrin (OTf2C) clearly resolve the C(2)H resonances of the five histidinyl residues in the protein. Formation of the Ga(III)OTf2C(anion) ternary complexes results in different chemical shift and titration behaviors for certain C(2)H resonances in the carbonato, oxalato, and malonato complexes. The pKa' of the imidazole group involved in a proton relay with the synergistic anion and a water of hydration appears to be anion independent. Thus the initial attack of a proton on the ternary complex appears to be at a ligand other than the anion or anion-bindmg imidazole group." @default.
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- W2085106867 date "1986-10-01" @default.
- W2085106867 modified "2023-10-03" @default.
- W2085106867 title "Effects of synergistic anions on the proton magnetic resonance spectra and ph titration of histidinyl side chains in the C-terminal half-molecule of ov" @default.
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- W2085106867 doi "https://doi.org/10.1016/0162-0134(86)80088-5" @default.
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