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• W2085129075 abstract "The density matrix of a spin I = 7/2, excited by a radiofrequency pulse, is calculated in taking into account the first order quadrupolar interaction during the excitation. Therefore, the results are valid for any ratio of the quadrupolar coupling ωQ to the pulse amplitude ωRF. The behaviour of the central line intensity versus the pulse length is discussed both in time and frequency domains. The quadrupolar coupling constant e 2 qQ/h = 8·24 MHz of the 59Co(III) nucleus in a polycrystalline sample of Na3[Co(NO2)6] is determined using this one-dimensional nutation method, and the lineshape reveals mainly the presence of chemical shift anisotropy with axial symmetry." @default.
• W2085129075 created "2016-06-24" @default.
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• W2085129075 date "1994-12-10" @default.
• W2085129075 modified "2023-10-10" @default.
• W2085129075 title "Exact expression for the spin 7/2 line intensities: Application to solid state ⁵⁹Co(III) NMR" @default.
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• W2085129075 doi "https://doi.org/10.1080/00268979400101721" @default.
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