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- W2085131651 abstract "Intrinsic viscosity, [η], weight-average molecular weight, Mw, relationships are reported for narrow molecular weight distribution linear polyisoprene and polystyrene samples in CCl4 at 25°C. Molecular weight values cover a range nearly two orders in magnitude, extending as low as 3 × 103. In the case of polystyrene there exists a molecular weight range (around Mw = 16,700) corresponding to a change in the Mark-Houwink-Sakurada (MHS) exponent from α = 0.71 to α = 0.54. Comparisons between the viscometric and hydrodynamic radii, from literature data, are made. For polyisoprene the MHS relationship is reported in CCl4, for the first time. For this case α = 0.713 for the whole range of molecular weights studied. Values for the second virial coefficient from low-angle light-scattering measurements support the conclusions drawn from viscometry that CCl4 is a good solvent for both polymers studied. The different behavior of the MHS exponent may be attributed to the difference in chain flexibility. © 1995 John Wiley & Sons, Inc." @default.
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- W2085131651 date "1995-11-30" @default.
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- W2085131651 title "Hydrodynamic behavior of anionically prepared linear polyisoprenes and polystyrenes in carbon tetrachloride" @default.
- W2085131651 doi "https://doi.org/10.1002/polb.1995.090331607" @default.
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