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- W2085132209 abstract "Herein we report the preparation of novel boronic acid-substituted 4,7-phenanthrolinium viologens and demonstrate their ability to quench the fluorescence of 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt (pyranine). In an aqueous buffer solution at pH 7.4, the quenching is suppressed upon binding to monosaccharides, as was determined by Stern−Volmer analysis. Thus, the combination of the viologen and pyranine is shown to act as a saccharide sensor. A spectroscopic study reveals a ground-state complexation between the viologens and pyranine. In the presence of monosaccharide, the complex dissociates, resulting in a relative increase in the fluorescence. In comparison to the dipyridyl-derived viologen, the phenanthroline-derived viologen shows a greater fluorescence quenching as well as sensitivity to and an unusual selectivity for glucose." @default.
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- W2085132209 date "2003-05-14" @default.
- W2085132209 modified "2023-10-18" @default.
- W2085132209 title "Monosaccharide Detection with 4,7-Phenanthrolinium Salts: Charge-Induced Fluorescence Sensing" @default.
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- W2085132209 doi "https://doi.org/10.1021/la034270h" @default.
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