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- W2085135254 abstract "A fitting procedure is descdribede to establish the conformation and molecular dynamics of flexible molecules co-ordinated to lanthanide cations from NMR paramagnetic shift data of 1H and 13C resonances. The results from L-proline and L-valine in aqueous solution at low pH values are consistent with peak assignments given by independent methods. A free rotation of the pyrrolidine ring is proposed in the case of L-proline, and a rigid lock in the case of L-valine, and angle and distance values are given for the cation and ligand positions in the complex." @default.
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- W2085135254 date "1980-04-01" @default.
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- W2085135254 title "Ligand conformation in lanthanide complexes by NMR paramagnetic shifts:L-proline andL-valine" @default.
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- W2085135254 doi "https://doi.org/10.1002/mrc.1270130415" @default.
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