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• W2085140559 abstract "Variable-temperature hyperpolarized (HP) 129Xe NMR spectroscopy has been employed to characterize surface properties of mesoporous MCM-41 modified by silylation treatment. The characteristic chemical shifts responsible for Xe−surface interactions exhibit strong correlations with both the surface coverage and chain length of the grafted alkylsilanes. Consequently, the deshielding medium contribution due to individual alkyl ligand can be deduced based on the group contribution analysis revealing the potential use of HP 129Xe NMR for probing the surface properties of organic-functionalized porous materials." @default.
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• W2085140559 date "2004-12-18" @default.
• W2085140559 modified "2023-09-27" @default.
• W2085140559 title "Probing the Alkyl Ligands on Silylated Mesoporous MCM-41 Using Hyperpolarized ¹²⁹Xe NMR Spectroscopy" @default.
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• W2085140559 doi "https://doi.org/10.1021/jp044984g" @default.
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