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- W2085148244 abstract "Two new types of iso-oxacephems have been synthesized in which a phosphonate group replaces either the carboxyl group or C(3). The latter compound exists as a stable trialkoxyphosphonium ylide.Potassium thioacetate and O2 in DMF are transformed in an autocatalytic, probably sulfur-catalyzed process to CH3COOK and sulfur; the latter two reagents are sufficient to transform the methanesulfonate 7 to the isopenam 15." @default.
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- W2085148244 date "1982-07-28" @default.
- W2085148244 modified "2023-09-24" @default.
- W2085148244 title "The Synthesis of 4-Decarboxy-4-phosphono-O-2-isooxacephems, -isopenams and -isooxacephems Containing Phosphorus at the 3-Position" @default.
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- W2085148244 doi "https://doi.org/10.1002/hlca.19820650505" @default.
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