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- W2085152209 abstract "The scrambling of the polarization of a light beam by the glass windows of a 25‐kbar hydrostatic Raman cell increases quadratically with the pressure up to 18 kbar, as expected from the theory of the photoelastic effect. When the laser beam passes along the cylinder axis of the window, the degree of scrambling by one window is 0.0022 at 18 kbar, but increases greatly as the laser beam shifts from the center of the window. The theory of the photoelastic effect was specialized to small depolarizations, and from it the mean stress distribution in the window was determined empirically from the degree of scrambling as a function of the radius. The effect of the scrambling on a Raman measurement, which needs a much larger aperture for the exit window than for the exciting laser beam, was estimated for two 90°‐scattering geometries by using the empirical stress distribution. The geometry Z(YZ)Y is particularly suitable because the inlet window produces a weak X‐polarized signal, which is largely rejected by the analyzer, and the strong Y‐polarized signal produces no scattering along the Y direction. The calculated degree of scrambling is <10−3 at 18 kbar. The depolarization of the symmetric stretching bands of carbon tetrachloride up to 1 kbar and of carbon disulphide up to 10 kbar has been measured and confirms this conclusion." @default.
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- W2085152209 date "1984-08-01" @default.
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- W2085152209 title "Polarization scrambling by the glass windows of a Raman cell up to 18 kbar" @default.
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- W2085152209 doi "https://doi.org/10.1063/1.1137915" @default.
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