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• W2085155035 startingPage "6700" @default.
• W2085155035 abstract "MnSe epilayers are grown on (001) GaAs substrates by molecular beam epitaxy (MBE), which exhibit NaCl structure as shown by x-ray diffraction. Their zone-center transverse optic (TO) and longitudinal optic (LO) phonons have been observed as minima in infrared transmission with oblique incidence, i.e., in the Berreman geometry, using Fourier transform infrared spectroscopy. In contrast, they are absent in the Raman spectrum, consistent with the rule of mutual exclusion. The TO and LO frequencies thus deduced, 139 and $239 {mathrm{cm}}^{ensuremath{-}1},$ respectively, differ significantly from the corresponding values of 219.5 and $257 {mathrm{cm}}^{ensuremath{-}1}$ obtained for zinc-blende MnSe. The latter were deduced from the $stackrel{ensuremath{rightarrow}}{x}1$ values of the TO and LO frequencies from a Raman study of MBE-grown ${mathrm{Cd}}_{1ensuremath{-}x}{mathrm{Mn}}_{x}mathrm{Se}$ epilayers. A similar study of ZnTe/MnSe multiple quantum well structure also yielded the LO at $249 {mathrm{cm}}^{ensuremath{-}1},$ compatible with the zinc-blende character of MnSe in such structures, combined with the strain experienced by them." @default.
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• W2085155035 date "1998-09-15" @default.
• W2085155035 modified "2023-10-12" @default.
• W2085155035 title "MnSe: Rocksalt versus zinc-blende structure" @default.
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• W2085155035 doi "https://doi.org/10.1103/physrevb.58.6700" @default.
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