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• W2085181721 abstract "The complex formation between a new synthesized Schiff base and the cations Ni2+, Co2+, Cu2+, and Zn2+ in ethanol, dimethylformamide (DMF), and acetonitrile (AN) was studied spectrophotometrically using rank annihilation factor analysis (RAFA). According to molar ratio data and Job’s plots, the stoichiometry of complexation between the Schiff base and the cations Co2+, Ni2+, and Zn2+ was 1:2, and that between the Schiff base and Cu2+ in all solvents and Zn2+ in AN was 1:1. Formation constants of these complexes were derived using RAFA on spectrophotometric data. In this process the contribution of the ligand is removed from the absorbance data matrix when the complex stability constant acts as an optimizing object, and simply combined with the pure spectrum of ligand, the rank of the original data matrix can be reduced by one by annihilating the information of the ligand from the original data matrix. Also the effect of surfactants such as sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB..." @default.
• W2085181721 created "2016-06-24" @default.
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• W2085181721 date "2010-08-03" @default.
• W2085181721 modified "2023-09-25" @default.
• W2085181721 title "Application of Rank Annihilation Factor Analysis to the Spectrophotometric Determination of the Formation Constants of Complexes of a New Schiff Base and Some Transition Metals in Different Media" @default.
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• W2085181721 doi "https://doi.org/10.1021/je1003516" @default.
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