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- W2085181743 abstract "The 5-methyldihydrothiazolo (3,2-c) pyrimidinium cation is evaporated as the corresponding anhydro base. In competition with anhydro base formation the 8-ethoxy derivative eliminates ethyl bromide to give the corresponding betaine. The latter appears to be electronically rearranged and evaporated as a covalent valence isomer. The 3-carboxy derivative investigated suffered decarboxylation and ring opening to a vinyl thione. In the absence of a pyrimidyl methyl group the thiazolo ring was attacked by the anion. The electronically induced fragmentations are discussed and used to deduce the structures of the pyrolytic products." @default.
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- W2085181743 date "1971-03-01" @default.
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- W2085181743 title "Mass spectrometry of onium compounds—VI: Pyrimidinium oxides" @default.
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- W2085181743 doi "https://doi.org/10.1002/oms.1210050311" @default.
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