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- W2085192534 startingPage "3130" @default.
- W2085192534 abstract "Substituted S-aryl and O-aryl N-arylthiocarbamates have been synthetized. Kinetic studies of hydrolysis of these compounds in 20% aqueous dioxane prove the E1cB mechanism. The found Hammett reaction constants, activation entropy values, Broensted coefficients, and comparison of reactivity with N-methyl analogues have been discussed as criteria of the mentioned mechanism. Hydrolysis results of thiocarbamates in the same medium are compared." @default.
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- W2085192534 date "1980-01-01" @default.
- W2085192534 modified "2023-09-24" @default.
- W2085192534 title "Hydrolysis kinetics and mechanism of diarylthiocarbamates in 20% aqueous dioxane medium" @default.
- W2085192534 doi "https://doi.org/10.1135/cccc19803130" @default.
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