FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085192600> ?p ?o ?g. }

• W2085192600 endingPage "7526" @default.
• W2085192600 startingPage "7519" @default.
• W2085192600 abstract "Dual carbon electrodes (DCEs) are quickly, easily, and cheaply fabricated by depositing pyrolytic carbon into a quartz theta nanopipet. The size of DCEs can be controlled by adjusting the pulling parameters used to make the nanopipet. When operated in generation/collection (G/C) mode, the small separation between the electrodes leads to reasonable collection efficiencies of ca. 30%. A three-dimensional finite element method (FEM) simulation is developed to predict the current response of these electrodes as a means of estimating the probe geometry. Voltammetric measurements at individual electrodes combined with generation/collection measurements provide a reasonable guide to the electrode size. DCEs are employed in a scanning electrochemical microscopy (SECM) configuration, and their use for both approach curves and imaging is considered. G/C approach curve measurements are shown to be particularly sensitive to the nature of the substrate, with insulating surfaces leading to enhanced collection efficiencies, whereas conducting surfaces lead to a decrease of collection efficiency. As a proof-of-concept, DCEs are further used to locally generate an artificial electron acceptor and to follow the flux of this species and its reduced form during photosynthesis at isolated thylakoid membranes. In addition, 2-dimensional images of a single thylakoid membrane are reported and analyzed to demonstrate the high sensitivity of G/C measurements to localized surface processes. It is finally shown that individual nanometer-size electrodes can be functionalized through the selective deposition of platinum on one of the two electrodes in a DCE while leaving the other one unmodified. This provides an indication of the future versatility of this type of probe for nanoscale measurements and imaging." @default.
• W2085192600 created "2016-06-24" @default.
• W2085192600 creator A5010645222 @default.
• W2085192600 creator A5019569012 @default.
• W2085192600 creator A5038254003 @default.
• W2085192600 creator A5042533864 @default.
• W2085192600 creator A5046324867 @default.
• W2085192600 creator A5063156360 @default.
• W2085192600 creator A5079989792 @default.
• W2085192600 creator A5086500417 @default.
• W2085192600 date "2013-07-08" @default.
• W2085192600 modified "2023-10-14" @default.
• W2085192600 title "Fabrication, Characterization, and Functionalization of Dual Carbon Electrodes as Probes for Scanning Electrochemical Microscopy (SECM)" @default.
• W2085192600 cites W1963959892 @default.
• W2085192600 cites W1965355140 @default.
• W2085192600 cites W1966236362 @default.
• W2085192600 cites W1969357101 @default.
• W2085192600 cites W1972286755 @default.
• W2085192600 cites W1974281754 @default.
• W2085192600 cites W1978218819 @default.
• W2085192600 cites W1979849903 @default.
• W2085192600 cites W1979923159 @default.
• W2085192600 cites W1987921328 @default.
• W2085192600 cites W2001902818 @default.
• W2085192600 cites W2008885276 @default.
• W2085192600 cites W2016807694 @default.
• W2085192600 cites W2018073656 @default.
• W2085192600 cites W2025897420 @default.
• W2085192600 cites W2028155300 @default.
• W2085192600 cites W2029956296 @default.
• W2085192600 cites W2030081332 @default.
• W2085192600 cites W2034172840 @default.
• W2085192600 cites W2037282446 @default.
• W2085192600 cites W2040977310 @default.
• W2085192600 cites W2042057394 @default.
• W2085192600 cites W2043279950 @default.
• W2085192600 cites W2045343641 @default.
• W2085192600 cites W2047949159 @default.
• W2085192600 cites W2057071182 @default.
• W2085192600 cites W2059516558 @default.
• W2085192600 cites W2060452710 @default.
• W2085192600 cites W2064121032 @default.
• W2085192600 cites W2065542744 @default.
• W2085192600 cites W2084146839 @default.
• W2085192600 cites W2090660766 @default.
• W2085192600 cites W2093130867 @default.
• W2085192600 cites W2103810173 @default.
• W2085192600 cites W2106684398 @default.
• W2085192600 cites W2128035284 @default.
• W2085192600 cites W2137315642 @default.
• W2085192600 cites W2142841520 @default.
• W2085192600 cites W2149171993 @default.
• W2085192600 cites W2161861999 @default.
• W2085192600 cites W2163516704 @default.
• W2085192600 cites W2166128672 @default.
• W2085192600 cites W2166233182 @default.
• W2085192600 cites W2334903774 @default.
• W2085192600 doi "https://doi.org/10.1021/ac401476z" @default.
• W2085192600 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3971958" @default.
• W2085192600 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23795948" @default.
• W2085192600 hasPublicationYear "2013" @default.
• W2085192600 type Work @default.
• W2085192600 sameAs 2085192600 @default.
• W2085192600 citedByCount "52" @default.
• W2085192600 countsByYear W20851926002014 @default.
• W2085192600 countsByYear W20851926002015 @default.
• W2085192600 countsByYear W20851926002016 @default.
• W2085192600 countsByYear W20851926002017 @default.
• W2085192600 countsByYear W20851926002018 @default.
• W2085192600 countsByYear W20851926002019 @default.
• W2085192600 countsByYear W20851926002020 @default.
• W2085192600 countsByYear W20851926002021 @default.
• W2085192600 countsByYear W20851926002022 @default.
• W2085192600 countsByYear W20851926002023 @default.
• W2085192600 crossrefType "journal-article" @default.
• W2085192600 hasAuthorship W2085192600A5010645222 @default.
• W2085192600 hasAuthorship W2085192600A5019569012 @default.
• W2085192600 hasAuthorship W2085192600A5038254003 @default.
• W2085192600 hasAuthorship W2085192600A5042533864 @default.
• W2085192600 hasAuthorship W2085192600A5046324867 @default.
• W2085192600 hasAuthorship W2085192600A5063156360 @default.
• W2085192600 hasAuthorship W2085192600A5079989792 @default.
• W2085192600 hasAuthorship W2085192600A5086500417 @default.
• W2085192600 hasBestOaLocation W20851926001 @default.
• W2085192600 hasConcept C113196181 @default.
• W2085192600 hasConcept C115537861 @default.
• W2085192600 hasConcept C127413603 @default.
• W2085192600 hasConcept C147789679 @default.
• W2085192600 hasConcept C159985019 @default.
• W2085192600 hasConcept C171250308 @default.
• W2085192600 hasConcept C17525397 @default.
• W2085192600 hasConcept C178790620 @default.
• W2085192600 hasConcept C185592680 @default.
• W2085192600 hasConcept C192562407 @default.
• W2085192600 hasConcept C26771246 @default.
• W2085192600 hasConcept C2779266040 @default.
• W2085192600 hasConcept C36759035 @default.
• W2085192600 hasConcept C42360764 @default.

• next