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• W2085193892 abstract "Abstract Dye sensitized solar cells performances using two organic dyes with fluorinated-benzothiadiazole spacer, 3-{5-[7-(5-{4-[Bis(9,9-dimethyl-9 H -fluoren-2-yl)-amino]-5-fluoro-phenyl}thiophen-2-yl)benzo-[1,2,5]thiadiazol-4-yl]thiophen-2-yl}-2-cyano acrylic acid ( JK-311 ) and 3-{5-[7-(5-{4-[Bis(9,9-dimethyl-9 H -fluoren-2-yl)-amino]-5,6-difluorophe-nyl}thiophen-2-yl)benzo-[1,2,5]thiadiazol-4-yl]thiophen-2-yl}-2-cyano acrylic acid ( JK-312 ), were systematically investigated by solar simulation equipment, stepped light-induced transient measurements of photocurrent and voltage, and electrochemical impedance spectroscopy. To investigate substituent effect of fluorine atom on benzothiadiazole, molecular orbital calculations of two dyes using a time dependent density functional theory model with B3LYP/3-31G* were also carried out. JK-312 showed a unique electronic transition from HOMO-1 to LUMO. Short circuit current and open-circuit voltage in DSSCs performances were increased by the introduction of fluorine atom into spacer segment, compared to fluorine-free dyes." @default.
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• W2085193892 date "2014-01-01" @default.
• W2085193892 modified "2023-09-24" @default.
• W2085193892 title "Substituent effect of fluorine atom on benzothiadiazole bridging unit in dye sensitized solar cells" @default.
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• W2085193892 doi "https://doi.org/10.1016/j.tet.2013.11.047" @default.
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