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- W2085194499 abstract "The sila-olefination reaction has been used to synthesize the first long-lived bis-silene t-BuMe2Si(Me3Si)Si(2,6-Ad)Si(SiMe3)SiMe2Bu-t (1). In this paper, we report the synthesis, spectroscopic data and some reactions of 1. Our experiments show that the elimination step of sila-olefination reaction is strongly accelerated in diethyl ether (and other ethers) relative to toluene and by increasing the steric bulk around the silicon center undergoing elimination." @default.
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- W2085194499 date "2003-11-01" @default.
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- W2085194499 title "Synthesis of the first long-lived bis-silene" @default.
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- W2085194499 doi "https://doi.org/10.1016/s0022-328x(03)00549-7" @default.
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