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- W2085194638 abstract "A solid-phase method for the introduction of a variety of different side chains into oligoribonucleotides is presented. It is based on a beta-D-allofuranosyl phosphoramidite with a bromopentyl-substituent tethered to the 6'-O position. After its incorporation into fully protected, immobilized RNA sequences, the bromine was substituted with a variety of soft nucleophiles which, in some cases, allowed further transformations. After deprotection and detachment, the corresponding functionalized oligoribonucleotides were purified and characterized. Incorporation of such side chains led to a slight lowering of transition temperatures, but some of them led to a significant enthalpic stabilization of an A-type RNA duplex." @default.
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- W2085194638 date "1999-10-22" @default.
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- W2085194638 title "Functionalization of the Sugar Moiety of Oligoribonucleotides on Solid Support" @default.
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- W2085194638 doi "https://doi.org/10.1021/bc9900901" @default.
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