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- W2085203903 abstract "Abstract Addition of benzyldi-2-pyridylamine and isoprene to a solution of [CU(O3SCF3)]2·C6H6 in THF yields Cu2[(C6H5CH2)N-(C5H4N)2]2(μ-C5H8)(O3SCF3)2, the title complex. This complex crystallizes in the triclinic space group P 1 with a = 11.721(4) A, b = 14.099(4) A, c = 14.179(4) A, α = 80.01(2), β = 78.17(2)°, γ = 71.80(2)°, V= 2063.6 A3, and Z = 2. The structure, which contains disordered triflate ligands, converged to an R = 0.086 and Rw = 0.132 for 2887 reflections of I⪢ 3σ,(Io). It exhibits the isoprene ligand in the s-trans configuration chelating η2 to both CuI atoms." @default.
- W2085203903 created "2016-06-24" @default.
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- W2085203903 date "1993-06-01" @default.
- W2085203903 modified "2023-09-22" @default.
- W2085203903 title "Bis(benzyldi-2-pyridylamine)-η′2,-η2-(s-trans-isoprene) dicopper(I) bistrifluoromethanesulfonate. A stable CuI-diene complex" @default.
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- W2085203903 doi "https://doi.org/10.1016/0022-328x(93)83202-7" @default.
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