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- W2085205097 abstract "Concentrations of inorganic, mercuric mercury (HgII), methyl mercury (MeHg) and ancillary chemistry measured in first-order streams draining 0−4 (N = 20) and 4−10 (N = 27) year-old clear-cuts of former Norway Spruce Picea abies (Karst.) forest stands were compared with concentrations in streams draining >70 year-old Norway Spruce reference stands (N = 10). Concentrations of MeHg, and ratios of MeHg TOC−1 and HgII TOC−1, were significantly (p < 0.01) elevated in 0−4 year-old clear-cuts, as compared to references. The only ancillary variable showing a significant elevation for 0−4 year-old clear-cuts was Mn (p < 0.02). The 4−10 year-old clear-cuts showed intermediate concentrations with nonsignificant differences as compared to references. pH, nitrate, sulfate, Ca, Fe, TOC, TON, and the aromaticity of TOC (SUVA254 nm) showed nonsignificant differences between clear-cut age classes and references. Assuming that MeHg and HgII are mobilized from soil to stream to a similar relative extent as a consequence of clear-cutting, a calculation showed that 1/6 of the elevated MeHg concentration was due to enhanced mobilization from soil and 5/6 was due to new methylation of HgII 0−4 years after clear-cut. New methylation after clear-cut is suggested to be stimulated by an increased availability of electron donors for methylating bacteria, as a consequence of degradation of logging residue (“slash”) and soil organic matter. A subdivision of sites situated above and below the highest postglacial coastline (HC) revealed a significant elevation of MeHg, MeHg TOC−1 and HgII TOC−1 (p < 0.05) beyond their references in 0−4 year-old clear-cuts above (but not below) the HC. This suggests that postglacial deposits of FeS(s) and FeS2(s) were not an important factor for elevation of MeHg after clear-cut." @default.
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- W2085205097 date "2009-10-05" @default.
- W2085205097 modified "2023-09-25" @default.
- W2085205097 title "Elevated Concentrations of Methyl Mercury in Streams after Forest Clear-Cut: A Consequence of Mobilization from Soil or New Methylation?" @default.
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- W2085205097 doi "https://doi.org/10.1021/es900996z" @default.
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