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- W2085205425 abstract "The origins for the abrupt adhesion loss at a critical relative humidity (RH) for polymeric adhesives bonded to inorganic surfaces were explored using a poly(methyl methacrylate) (PMMA) film on silicon oxide as a model system. The interfacial and bulk water concentrations within the polymer film were quantified as a function of D2O partial pressure using neutron reflectivity. The adhesive fracture energies of these PMMA/SiO2 interfaces at the same conditions were determined using a shaft-loaded blister test. Discontinuities in the adhesive fracture energy, bulk moisture solubility, and the width of the interfacial moisture excess near the interface were observed at the critical RH. A mechanism based on the coupling of bulk swelling-induced stresses with the decreased cohesive strength due to moisture accumulation at the interface is proposed and is consistent with all experimental observations." @default.
- W2085205425 created "2016-06-24" @default.
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- W2085205425 date "2008-04-29" @default.
- W2085205425 modified "2023-09-27" @default.
- W2085205425 title "Fundamentals of Adhesion Failure for a Model Adhesive (PMMA/Glass) Joint in Humid Environments" @default.
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- W2085205425 doi "https://doi.org/10.1080/00218460802004428" @default.
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