Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085208577> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2085208577 endingPage "H769" @default.
- W2085208577 startingPage "H765" @default.
- W2085208577 abstract "The electrochemical behavior of a biologically important phenazine derivative, 1-methoxyphenazine (MPZ) was scrutinized over a pH range 1.2–12.8 by cyclic, square wave and differential pulse voltammetry. The results of cathodic peak potential shift as a function of pH demonstrated that 1-methoxy phenazine is reduced by a 1e − ,1 H + diffusion controlled process. Epc − Epc/2 values, scan rate dependent deviation of peak potential, heterogeneous electron transfer rate constant and inequality of the components of total current proved the quasi-reversible nature of the redox process. MPZ was found to oxidize in the pH range 5–12.8 by the loss of a single electron without proton involvement. The pKa of MPZ with a value of 11.2 was determined from the intersection of the two segments of Ep vs. pH plot. The pKa values of MPZ obtained from all the three electrochemical techniques were found in very good agreement. The limits of detection and quantification of 1-methoxyphenazine were determined as 2.6 μ Ma nd 8.6 μM respectively. On the basis of the results obtained redox mechanism was proposed with the objective of emphasizing imperative aspects of structure-activity relationships and understanding the unexplored pathways by which this class of compounds exert its biochemical actions." @default.
- W2085208577 created "2016-06-24" @default.
- W2085208577 creator A5001893788 @default.
- W2085208577 creator A5030379127 @default.
- W2085208577 creator A5049362443 @default.
- W2085208577 creator A5059389165 @default.
- W2085208577 creator A5068221435 @default.
- W2085208577 creator A5072783254 @default.
- W2085208577 creator A5081551071 @default.
- W2085208577 creator A5090949562 @default.
- W2085208577 date "2013-01-01" @default.
- W2085208577 modified "2023-09-25" @default.
- W2085208577 title "Detailed Electrochemical Probing of the pH Dependent Redox Behavior of 1-methoxyphenazine" @default.
- W2085208577 cites W1575461149 @default.
- W2085208577 cites W1974571561 @default.
- W2085208577 cites W1977050273 @default.
- W2085208577 cites W2014529027 @default.
- W2085208577 cites W2014604638 @default.
- W2085208577 cites W2016069685 @default.
- W2085208577 cites W2022533696 @default.
- W2085208577 cites W2031427610 @default.
- W2085208577 cites W2033507368 @default.
- W2085208577 cites W2043148623 @default.
- W2085208577 cites W2047581380 @default.
- W2085208577 cites W2065351266 @default.
- W2085208577 cites W2078995471 @default.
- W2085208577 cites W2082652649 @default.
- W2085208577 cites W2091902431 @default.
- W2085208577 cites W2157631104 @default.
- W2085208577 cites W2157931918 @default.
- W2085208577 cites W2165899766 @default.
- W2085208577 cites W2476983109 @default.
- W2085208577 cites W2489179305 @default.
- W2085208577 cites W4246703877 @default.
- W2085208577 doi "https://doi.org/10.1149/2.097310jes" @default.
- W2085208577 hasPublicationYear "2013" @default.
- W2085208577 type Work @default.
- W2085208577 sameAs 2085208577 @default.
- W2085208577 citedByCount "6" @default.
- W2085208577 countsByYear W20852085772014 @default.
- W2085208577 countsByYear W20852085772015 @default.
- W2085208577 countsByYear W20852085772018 @default.
- W2085208577 countsByYear W20852085772019 @default.
- W2085208577 countsByYear W20852085772020 @default.
- W2085208577 crossrefType "journal-article" @default.
- W2085208577 hasAuthorship W2085208577A5001893788 @default.
- W2085208577 hasAuthorship W2085208577A5030379127 @default.
- W2085208577 hasAuthorship W2085208577A5049362443 @default.
- W2085208577 hasAuthorship W2085208577A5059389165 @default.
- W2085208577 hasAuthorship W2085208577A5068221435 @default.
- W2085208577 hasAuthorship W2085208577A5072783254 @default.
- W2085208577 hasAuthorship W2085208577A5081551071 @default.
- W2085208577 hasAuthorship W2085208577A5090949562 @default.
- W2085208577 hasConcept C127413603 @default.
- W2085208577 hasConcept C147789679 @default.
- W2085208577 hasConcept C171250308 @default.
- W2085208577 hasConcept C17525397 @default.
- W2085208577 hasConcept C179104552 @default.
- W2085208577 hasConcept C185592680 @default.
- W2085208577 hasConcept C192562407 @default.
- W2085208577 hasConcept C42360764 @default.
- W2085208577 hasConcept C52859227 @default.
- W2085208577 hasConcept C55904794 @default.
- W2085208577 hasConceptScore W2085208577C127413603 @default.
- W2085208577 hasConceptScore W2085208577C147789679 @default.
- W2085208577 hasConceptScore W2085208577C171250308 @default.
- W2085208577 hasConceptScore W2085208577C17525397 @default.
- W2085208577 hasConceptScore W2085208577C179104552 @default.
- W2085208577 hasConceptScore W2085208577C185592680 @default.
- W2085208577 hasConceptScore W2085208577C192562407 @default.
- W2085208577 hasConceptScore W2085208577C42360764 @default.
- W2085208577 hasConceptScore W2085208577C52859227 @default.
- W2085208577 hasConceptScore W2085208577C55904794 @default.
- W2085208577 hasIssue "10" @default.
- W2085208577 hasLocation W20852085771 @default.
- W2085208577 hasOpenAccess W2085208577 @default.
- W2085208577 hasPrimaryLocation W20852085771 @default.
- W2085208577 hasRelatedWork W1981292136 @default.
- W2085208577 hasRelatedWork W1987234305 @default.
- W2085208577 hasRelatedWork W2020993114 @default.
- W2085208577 hasRelatedWork W2021099451 @default.
- W2085208577 hasRelatedWork W2312579622 @default.
- W2085208577 hasRelatedWork W2408045751 @default.
- W2085208577 hasRelatedWork W2748952813 @default.
- W2085208577 hasRelatedWork W2899084033 @default.
- W2085208577 hasRelatedWork W3137452781 @default.
- W2085208577 hasRelatedWork W4232552561 @default.
- W2085208577 hasVolume "160" @default.
- W2085208577 isParatext "false" @default.
- W2085208577 isRetracted "false" @default.
- W2085208577 magId "2085208577" @default.
- W2085208577 workType "article" @default.