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- W2085208836 abstract "Abstract Auger and electron energy-loss spectroscopies (ELS) have been used to study chemical states at the fracture surfaces of iron-phosphorus alloys. The transgranular (TG) and intergranular (IG) fracture planes have similar Auger P LVV transition energies and similar Fe 3 p loss energies. These indicate that phosphorus and iron atoms are dispersed atomically in layers segregated at IG planes. The energy separations between the inter-and intra-atomic Auger transition peaks in P LVV show that the TG and IG planes and Fe 3 P have similar energy separations between the P 3 p and Fe 3 p levels. The layers segregated at IG planes are estimated to be equivalent to a monolayer, as indicated by the dependence of the loss energy of the valence-conduction-band transition on primary-electron kinetic energy from 200 to 500 eV. The phosphorus concentration in the segregated layers is saturated to ~ 20 at.% above a bulk phosphorus concentration of 2 at.%." @default.
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- W2085208836 date "1984-01-01" @default.
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- W2085208836 title "Study of chemical states at intergranular fracture planes of iron-phosphorus alloys by auger and electron energy-loss spectroscopies" @default.
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- W2085208836 doi "https://doi.org/10.1016/0368-2048(84)80059-6" @default.
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