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- W2085228492 abstract "Bridged macrocyclic transition metal complexes using phthalocyanine and naphthalocyanine macrocycles e.g. [PcM(L)]n with M = Fe, Ru, Co and L = e.g. pyz, dib, tz, SCN−, CN− have been synthesized and their electrical properties studied in detail. Regardless of the bridging ligand stable semiconducting compounds are formed after doping with iodine. Some of these e.g. [PcM(tz)]n, M = Fe, Ru or e.g. [PcM(L)]n, M = Fe, Co; L = CN−, SCN− exhibit good semiconducting properties without additional doping. Substituted phthalocyanines (R4PcM where R = t-Bu, Et, CH2OC12H25, C5H11-C8H17) were also synthesized and were found to be more soluble in organic solvents. The characterization of the phthalocyanines prepared were carried out by IR, UV, 1H-NMR and Mößbauer (Fe) spectroscopy." @default.
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- W2085228492 date "1994-03-01" @default.
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- W2085228492 title "Conduction in polymeric macrocyclic complexes" @default.
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- W2085228492 doi "https://doi.org/10.1002/masy.19940800107" @default.
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