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- W2085237130 abstract "In relation with the photochemical mechanism of sulfochloration of trifluoromethane ab initio (SCF+CI) calculations were performed on CF3SO2• and CH3SO2• radicals. With optimization of all geometrical parameters the exothermicity of the formati reactions CF3•+SO2→CF3SO2• and CH3•+SO2→CH3SO2• were evaluated. For CH3SO2• a experimental data; the low exothermicity calculated for CF3SO2• indicates a dissociation stability clearly reduced in comparison with that for CH3SO2•." @default.
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- W2085237130 date "1989-07-01" @default.
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- W2085237130 title "Sulfochloration of trifluoromethane. Theoretical study of the trifluoromethane sulfonyl radical" @default.
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- W2085237130 doi "https://doi.org/10.1016/0301-0104(89)87007-7" @default.
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