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- W2085244557 abstract "LiMn2O4 was examined as a cathode material for the lithium-ion battery, working together with a room temperature ionic liquid electrolyte, obtained by dissolution of solid lithium bis(trifluoromethanesulphonyl)imide (LiNTf2) in liquid N-methyl-N-propylpyrrolidinium bis (trifluoromethanesulphonyl) imide (MePrPyrNTf2) with and without gamma-butyrolactone (GBL). The Li/LiMn2O4 cell was tested by cyclic voltammetry, galvanostatic charging/discharging, and with impedance spectroscopy. In the cyclic voltammograms for these electrolytes pairs of oxidation current peaks and reduction current peaks for the cathode are distinct, revealing typical characteristics of two-stage reversible-phase transformation of the spinel. The LiMn2O4 cathode showed good cyclability and Coulombic efficiency (126 mAh g−1 after 50 cycles) working together with 0.7 M LiNTf2 in MePrPyrNTf2 + 10 wt%. GBL ionic liquid electrolyte. At the C/7and C/5 rates, the LiMn2O4 showed stable capacities of 124 and 120 mAh g−1, respectively. Scanning electron microscopy images of pristine electrodes and those taken after electrochemical cycling showed changes which may be interpreted as a result of solid electrolyte interphase formation. The 0.7 M LiNTf2 in MePrPyrNTf2 and 0.7 M LiNTf2 in MePrPyrNTf2 + 10 wt%. GBL electrolytes have a greater thermal stability range (no peak is observed below 230 °C)." @default.
- W2085244557 created "2016-06-24" @default.
- W2085244557 creator A5078349908 @default.
- W2085244557 date "2013-12-21" @default.
- W2085244557 modified "2023-10-18" @default.
- W2085244557 title "Properties of LiMn2O4 cathode in electrolyte based on ionic liquid with and without gamma-butyrolactone" @default.
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- W2085244557 doi "https://doi.org/10.1007/s10008-013-2360-4" @default.
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