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- W2085244570 abstract "The complex [Mo(CO)3(η-C5Me5){P(OMe)3}]BF4(1) reacts in methanol solution with Na(OMe) to give a mixture of cis- and trans-[Mo(CO)2(η-C5Me5){P(OMe)3}(CO2Me)](3). Compound (3) decarbonylates at room temperature in various solvents giving a mixture of cis- and trans-[Mo(CO)2(η-C5Me5){P(OMe)3}(OMe)](4). The complex [Mo(CO)3(η-C5Me5)] BF4(2) reacts in methanol solution with Na(OMe) affording the insoluble complex [{Mo(CO)2(η-C5Me5)(OMe)}n](5) which is monomerized by reaction with P(OMe)3 in refluxing tetrahydrofuran (thf); trans-(4) is the main product of this reaction. Oxidation of a thf suspension of [{Mo(CO)2(η-C5Me5)(OMe)}n] by oxygen gives the MoVI derivative [{Mo(η-C5Me5)(O)2}2(µ-O)](6), together with unidentified products. The X-ray crystal structure of (6) has been established: (6) is monoclinic, space group P21/a, a= 17.677(6), b= 9.248(1), c= 21.272(6)Å, β= 101.68(2)°, Z= 6." @default.
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- W2085244570 date "1989-01-01" @default.
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- W2085244570 title "Reactivity of cationic molybdenum(<scp>II</scp>) complexes. Part 3. Synthesis of methoxide and carbomethoxide derivatives of η-pentamethylcyclopentadienyl–molybdenum(<scp>II</scp>) and the crystal structure determination of the oxidation product trans-[{Mo(η-C<sub>5</sub>Me<sub>5</sub>)(O)<sub>2</sub>}<sub>2</sub>(µ-O)]" @default.
- W2085244570 doi "https://doi.org/10.1039/dt9890000155" @default.
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