FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085249628> ?p ?o ?g. }

• W2085249628 endingPage "98" @default.
• W2085249628 startingPage "90" @default.
• W2085249628 abstract "[MX2(CO)3(DAB)] (M = Mo, W; X = I, Br) (5–8) complexes bearing the 1,4-diazobutadiene (DAB) ligand RNC(Ph)C(Ph)NR [R = (CH2)3Si(OEt)3] were immobilized in MCM-41 mesoporous silica. The tethering, stepwise procedure started with treatment of the MCM-41 mesoporous material with a toluene solution of the 1,4-diazobutadiene ligand, under reflux. The molybdenum and tungsten organometallic cores were subsequently introduced into the ligand-silicas by pore volume impregnation of a solution of the complexes [MX2(CO)3(NCMe)2] (M = Mo, W; X = Br, I). The modified materials were extensively characterized by several techniques, such as FTIR, solid-state MAS and CP MAS NMR (13C, 29Si), powder XRD, and nitrogen adsorption–desorption measurements. These new materials (containing 2.6–2.9 wt.% Mo or 0.4–0.6 wt.% W) catalyze the ring-opening metathesis polymerization (ROMP) of norbornene (NBE) and norbornadiene at 328 K, in contrast with the very low activity exhibited by the precursor complexes and with their behavior at lower temperature. Addition of AlCl3 as a co-catalyst enhanced the catalytic performance of the material MCM-DAB-MoBr2 (12) in the ROMP of NBE." @default.
• W2085249628 created "2016-06-24" @default.
• W2085249628 creator A5004366372 @default.
• W2085249628 creator A5015271080 @default.
• W2085249628 creator A5048190312 @default.
• W2085249628 creator A5048643321 @default.
• W2085249628 creator A5051776486 @default.
• W2085249628 creator A5075659160 @default.
• W2085249628 date "2006-08-01" @default.
• W2085249628 modified "2023-09-27" @default.
• W2085249628 title "Hepta-coordinate halocarbonyl molybdenum(II) and tungsten(II) complexes as heterogeneous polymerization catalysts" @default.
• W2085249628 cites W1553501310 @default.
• W2085249628 cites W1595006058 @default.
• W2085249628 cites W1963773443 @default.
• W2085249628 cites W1966516097 @default.
• W2085249628 cites W1967028773 @default.
• W2085249628 cites W1969881306 @default.
• W2085249628 cites W1974774494 @default.
• W2085249628 cites W1982784029 @default.
• W2085249628 cites W1988141826 @default.
• W2085249628 cites W1998109680 @default.
• W2085249628 cites W2005181552 @default.
• W2085249628 cites W2005904182 @default.
• W2085249628 cites W2007981150 @default.
• W2085249628 cites W2010969259 @default.
• W2085249628 cites W2019949527 @default.
• W2085249628 cites W2039241045 @default.
• W2085249628 cites W2042602209 @default.
• W2085249628 cites W2052469052 @default.
• W2085249628 cites W2054111649 @default.
• W2085249628 cites W2060840945 @default.
• W2085249628 cites W2061489507 @default.
• W2085249628 cites W2068280652 @default.
• W2085249628 cites W2071016624 @default.
• W2085249628 cites W2073346200 @default.
• W2085249628 cites W2074834095 @default.
• W2085249628 cites W2075802779 @default.
• W2085249628 cites W2088527503 @default.
• W2085249628 cites W2089012282 @default.
• W2085249628 cites W2093586885 @default.
• W2085249628 cites W2103637866 @default.
• W2085249628 cites W2166862648 @default.
• W2085249628 cites W2322249250 @default.
• W2085249628 cites W2952533743 @default.
• W2085249628 doi "https://doi.org/10.1016/j.molcata.2006.04.023" @default.
• W2085249628 hasPublicationYear "2006" @default.
• W2085249628 type Work @default.
• W2085249628 sameAs 2085249628 @default.
• W2085249628 citedByCount "28" @default.
• W2085249628 countsByYear W20852496282012 @default.
• W2085249628 countsByYear W20852496282013 @default.
• W2085249628 countsByYear W20852496282014 @default.
• W2085249628 countsByYear W20852496282015 @default.
• W2085249628 countsByYear W20852496282016 @default.
• W2085249628 countsByYear W20852496282017 @default.
• W2085249628 countsByYear W20852496282018 @default.
• W2085249628 countsByYear W20852496282019 @default.
• W2085249628 countsByYear W20852496282021 @default.
• W2085249628 countsByYear W20852496282022 @default.
• W2085249628 crossrefType "journal-article" @default.
• W2085249628 hasAuthorship W2085249628A5004366372 @default.
• W2085249628 hasAuthorship W2085249628A5015271080 @default.
• W2085249628 hasAuthorship W2085249628A5048190312 @default.
• W2085249628 hasAuthorship W2085249628A5048643321 @default.
• W2085249628 hasAuthorship W2085249628A5051776486 @default.
• W2085249628 hasAuthorship W2085249628A5075659160 @default.
• W2085249628 hasConcept C116569031 @default.
• W2085249628 hasConcept C13965031 @default.
• W2085249628 hasConcept C153914509 @default.
• W2085249628 hasConcept C161790260 @default.
• W2085249628 hasConcept C170493617 @default.
• W2085249628 hasConcept C174499055 @default.
• W2085249628 hasConcept C178790620 @default.
• W2085249628 hasConcept C179104552 @default.
• W2085249628 hasConcept C185592680 @default.
• W2085249628 hasConcept C188027245 @default.
• W2085249628 hasConcept C2777496208 @default.
• W2085249628 hasConcept C2778142098 @default.
• W2085249628 hasConcept C2778827576 @default.
• W2085249628 hasConcept C2780227895 @default.
• W2085249628 hasConcept C2780547246 @default.
• W2085249628 hasConcept C2780669175 @default.
• W2085249628 hasConcept C44228677 @default.
• W2085249628 hasConcept C521977710 @default.
• W2085249628 hasConcept C542268612 @default.
• W2085249628 hasConcept C549387045 @default.
• W2085249628 hasConcept C55493867 @default.
• W2085249628 hasConcept C82776694 @default.
• W2085249628 hasConceptScore W2085249628C116569031 @default.
• W2085249628 hasConceptScore W2085249628C13965031 @default.
• W2085249628 hasConceptScore W2085249628C153914509 @default.
• W2085249628 hasConceptScore W2085249628C161790260 @default.
• W2085249628 hasConceptScore W2085249628C170493617 @default.
• W2085249628 hasConceptScore W2085249628C174499055 @default.
• W2085249628 hasConceptScore W2085249628C178790620 @default.
• W2085249628 hasConceptScore W2085249628C179104552 @default.
• W2085249628 hasConceptScore W2085249628C185592680 @default.
• W2085249628 hasConceptScore W2085249628C188027245 @default.

• next