Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085259608> ?p ?o ?g. }
- W2085259608 endingPage "4430" @default.
- W2085259608 startingPage "4424" @default.
- W2085259608 abstract "The oxidative behavior of bithiazole-ethylenedioxythiophene co-oligomers is described. The acceptor−donor−acceptor (A−D−A) compounds, 5,5‘-bis(4,4‘-dialkyl-2,2‘-bithiazol-5-yl)-(3,4,3‘,4‘-bis(ethylenedioxy)-2,2‘-dithienyl) (1, 2), are sequentially oxidized by NOBF4 through the paramagnetic monocation to the diamagnetic dication. The monocations form diamagnetic π-dimers, the allowed π−π electronic transitions of which are interpreted in terms of molecular exciton theory to give nearest-neighbor exciton coupling constants, J ≅ 0.2 eV. The spectra of the dications show that they are bipolarons; that is, the two charges share a common lattice deformation. The D−A−D co-oligomers, 5,5‘-bis(3,4-ethylenedioxythien-2-yl)-4,4‘-dibutyl-2,2‘-bithiazole (3) and 5,5‘-bis(3,4,3‘,4‘-bis(ethylenedioxy)-2,2‘-dithien-5-yl)-4,4‘-dibutyl-2,2‘-bithiazole (4), are oxidized in a single step to the corresponding bipolarons." @default.
- W2085259608 created "2016-06-24" @default.
- W2085259608 creator A5025348317 @default.
- W2085259608 creator A5037317469 @default.
- W2085259608 date "2003-10-10" @default.
- W2085259608 modified "2023-10-09" @default.
- W2085259608 title "Polarons, Bipolarons, and π-Dimers of Bis(3,4-ethylene-dioxythiophene)-(4,4‘-dialkyl-2,2‘-bithiazole)- <i>co</i>-Oligomers. Direct Measure of the Intermolecular Exciton Transfer Interaction" @default.
- W2085259608 cites W1851174798 @default.
- W2085259608 cites W1970791456 @default.
- W2085259608 cites W1973352382 @default.
- W2085259608 cites W1976888797 @default.
- W2085259608 cites W1979480939 @default.
- W2085259608 cites W1982082567 @default.
- W2085259608 cites W1992169779 @default.
- W2085259608 cites W1997686555 @default.
- W2085259608 cites W1999375755 @default.
- W2085259608 cites W2003497927 @default.
- W2085259608 cites W2004515385 @default.
- W2085259608 cites W2011086860 @default.
- W2085259608 cites W2012271740 @default.
- W2085259608 cites W2014009606 @default.
- W2085259608 cites W2016747827 @default.
- W2085259608 cites W2018829588 @default.
- W2085259608 cites W2021067714 @default.
- W2085259608 cites W2021861228 @default.
- W2085259608 cites W2024753854 @default.
- W2085259608 cites W2027006844 @default.
- W2085259608 cites W2029088279 @default.
- W2085259608 cites W2030200105 @default.
- W2085259608 cites W2036794525 @default.
- W2085259608 cites W2038361858 @default.
- W2085259608 cites W2041404693 @default.
- W2085259608 cites W2042339933 @default.
- W2085259608 cites W2046435506 @default.
- W2085259608 cites W2051206787 @default.
- W2085259608 cites W2064468729 @default.
- W2085259608 cites W2064505204 @default.
- W2085259608 cites W2067211621 @default.
- W2085259608 cites W2068564152 @default.
- W2085259608 cites W2080545274 @default.
- W2085259608 cites W2081796013 @default.
- W2085259608 cites W2083386084 @default.
- W2085259608 cites W2085087412 @default.
- W2085259608 cites W2086077751 @default.
- W2085259608 cites W2093239008 @default.
- W2085259608 cites W2141008036 @default.
- W2085259608 cites W2146101168 @default.
- W2085259608 cites W2159100472 @default.
- W2085259608 cites W2167121966 @default.
- W2085259608 cites W2950929783 @default.
- W2085259608 cites W2951384269 @default.
- W2085259608 cites W2952689075 @default.
- W2085259608 cites W2953051511 @default.
- W2085259608 cites W4229981230 @default.
- W2085259608 cites W4242591046 @default.
- W2085259608 doi "https://doi.org/10.1021/cm034484k" @default.
- W2085259608 hasPublicationYear "2003" @default.
- W2085259608 type Work @default.
- W2085259608 sameAs 2085259608 @default.
- W2085259608 citedByCount "31" @default.
- W2085259608 countsByYear W20852596082012 @default.
- W2085259608 countsByYear W20852596082015 @default.
- W2085259608 countsByYear W20852596082016 @default.
- W2085259608 countsByYear W20852596082017 @default.
- W2085259608 countsByYear W20852596082020 @default.
- W2085259608 countsByYear W20852596082021 @default.
- W2085259608 crossrefType "journal-article" @default.
- W2085259608 hasAuthorship W2085259608A5025348317 @default.
- W2085259608 hasAuthorship W2085259608A5037317469 @default.
- W2085259608 hasConcept C115260700 @default.
- W2085259608 hasConcept C121332964 @default.
- W2085259608 hasConcept C124712363 @default.
- W2085259608 hasConcept C147120987 @default.
- W2085259608 hasConcept C166950319 @default.
- W2085259608 hasConcept C17729963 @default.
- W2085259608 hasConcept C178790620 @default.
- W2085259608 hasConcept C185592680 @default.
- W2085259608 hasConcept C188027245 @default.
- W2085259608 hasConcept C26873012 @default.
- W2085259608 hasConcept C2778667255 @default.
- W2085259608 hasConcept C2779158978 @default.
- W2085259608 hasConcept C2779892579 @default.
- W2085259608 hasConcept C32909587 @default.
- W2085259608 hasConcept C55637122 @default.
- W2085259608 hasConcept C62520636 @default.
- W2085259608 hasConcept C64127065 @default.
- W2085259608 hasConcept C66009135 @default.
- W2085259608 hasConcept C75473681 @default.
- W2085259608 hasConcept C8010536 @default.
- W2085259608 hasConcept C96026104 @default.
- W2085259608 hasConceptScore W2085259608C115260700 @default.
- W2085259608 hasConceptScore W2085259608C121332964 @default.
- W2085259608 hasConceptScore W2085259608C124712363 @default.
- W2085259608 hasConceptScore W2085259608C147120987 @default.
- W2085259608 hasConceptScore W2085259608C166950319 @default.
- W2085259608 hasConceptScore W2085259608C17729963 @default.
- W2085259608 hasConceptScore W2085259608C178790620 @default.
- W2085259608 hasConceptScore W2085259608C185592680 @default.