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• W2085273668 startingPage "127" @default.
• W2085273668 abstract "Simultaneous thermogravimetry and differential thermal analysis data are presented for yttrium and the tervalent lanthanide oxalate decahydrates (Y, La - Er excluding Pm) and hexahydrates (Y, Er - Lu). The dehydration and the oxalate and intermediate dioxycarbonate decomposition of these two series of isomorphs show systematic trends which are discussed with reference to the stereochemical and bonding effects resulting from the lanthanide contraction. Anomalies in behaviour primarily arise from changes in the oxidation states of the cations during decomposition. Thermal analyses of co-precipitated cerium-terbium and yttrium-europium oxalate decahydrates indicate that the crystalline solid solutions so formed are thermally distinct species which show non-additive decomposition behaviour intermediate between those of the parent oxalates." @default.
• W2085273668 created "2016-06-24" @default.
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• W2085273668 date "1980-04-01" @default.
• W2085273668 modified "2023-10-12" @default.
• W2085273668 title "Thermal analysis of the oxalate hexahydrates and decahydrates of yttrium and the lanthanide elements" @default.
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• W2085273668 doi "https://doi.org/10.1016/0022-5088(80)90222-2" @default.
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