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- W2085301818 abstract "The short range structure of ternary sodium–copper–phosphate [(40–70)P2O5–(0–60)Na2O–(0–50)CuO (mol%)] samples were examined by Fourier-transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The XPS O 1s spectrum was deconvoluted into three components, symmetric bridging oxygen (P–O–P), non-bridging oxygen ( and PO) and asymmetric bridging oxygen (P–O–Cu). In the ultraphosphate and metaphosphate glasses, the P–O–Cu bonds are formed replacing bonds while keeping the same fraction of P–O–P bonds as Na2O is replaced by CuO. Whereas, in the polyphosphate glasses, the formation of P–O–Cu will replace both P–O–P and bonds. The results reveal the formation of P–O–Cu bonds in these glasses, and an increase of crosslink density. Thus, chemical durability and Tg of the glasses are increased." @default.
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- W2085301818 date "1999-03-01" @default.
- W2085301818 modified "2023-10-18" @default.
- W2085301818 title "FTIR and XPS studies of P2O5–Na2O–CuO glasses" @default.
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- W2085301818 doi "https://doi.org/10.1016/s0022-3093(99)00011-3" @default.
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