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• W2085309611 abstract "Coordination of P,N indolyl-phosphine ligands to AuI, AgI and CuI metal ions under weakly basic conditions results in easy deprotonation of the indolyl N–H function and effective formation of a family of homo- and heterobimetallic complexes MM′(PPh2C9H7N)2 (M = M′ = Au (2), Ag (5); M = Au, M′ = Cu (3), Ag (4)). The latter (4) exists as an inseparable mixture of four different complexes, which are in equilibrium driven by slow dynamics. The reaction of silver(I) and copper(I) ions with PPh2(C9H8N) affords a rare tetranuclear Z-shaped cluster Ag2Cu2(PPh2C9H7N)4 (6), which exhibits red luminescence in solid state (650 nm) and a weak dual emission in solution with the main component in the near-IR region (746 nm)." @default.
• W2085309611 created "2016-06-24" @default.
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• W2085309611 date "2011-01-01" @default.
• W2085309611 modified "2023-09-25" @default.
• W2085309611 title "Coinage metal complexes of 2-diphenylphosphino-3-methylindole" @default.
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• W2085309611 doi "https://doi.org/10.1039/c1dt10564g" @default.
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