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- W2085332871 abstract "A novel method is presented whereby the parameters quantifying the conductivity of an ionomer can be extracted from the phenomenon of electrode polarization in the dielectric loss and tanδ planes. Mobile ion concentrations and ion mobilities were determined for a poly(ethylene oxide)-based sulfonated ionomer with Li+, Na+, and Cs+ cations. The validity of the model was confirmed by examining the effects of sample thickness and temperature. The Vogel-Fulcher-Tammann (VFT)-type temperature dependence of conductivity was found to arise from the Arrhenius dependence of ion concentration and VFT behavior of mobility. The ion concentration activation energy was found to be 25.2, 23.4, and 22.3±0.5kJ∕mol for ionomers containing Li+, Na+, and Cs+, respectively. The theoretical binding energies were also calculated and found to be ∼5kJ∕mol larger than the experimental activation energies, due to stabilization by coordination with polyethylene glycol segments. Surprisingly, the fraction of mobile ions was found to be very small, <0.004% of the cations in the Li+ ionomer at 20°C." @default.
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- W2085332871 date "2006-04-11" @default.
- W2085332871 modified "2023-10-16" @default.
- W2085332871 title "Modeling electrode polarization in dielectric spectroscopy: Ion mobility and mobile ion concentration of single-ion polymer electrolytes" @default.
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- W2085332871 doi "https://doi.org/10.1063/1.2186638" @default.
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