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- W2085346068 abstract "A series of ether-derivatized imidazolium halides have been prepared and characterized. Contrary to literature reports, they are all crystalline solids and have melting points well above room temperature (50−100 °C). Single crystals of the imidazolium salts, obtained in situ by slow cooling from their molten state to room temperature, were analyzed by X-ray crystallography, revealing various anion−cation interactions in the solid state. Exchange of the halides with [Tf2N]- yielded room temperature ionic liquids with viscosities that are comparable to related 1-alkyl-3-methylimidazolium ionic liquids. Density functional theory combined with IR spectroscopy has been used to analyze the role of functionalization of the imidazolium side chain on the formation of the molecular and supramolecular structure of the compounds and its possible impact on their physical properties." @default.
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- W2085346068 date "2007-08-01" @default.
- W2085346068 modified "2023-10-02" @default.
- W2085346068 title "Revisiting Ether-Derivatized Imidazolium-Based Ionic Liquids" @default.
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- W2085346068 doi "https://doi.org/10.1021/jp073419l" @default.
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