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- W2085361503 abstract "In this paper the thermodynamic properties of two important extractants in hydrometallurgy (D2EHPA and EHEHPA) are studied. The activity coefficients of various diluents in D2EHPA-hydrocarbon binary systems are measured by gas chromatographic headspace analysis. The experimental data are regressed by using the Scatchard-Hildebrand solution theory. After revision of the mixing entropy, departures from the geometric mean of the cohesive energy are determined. Some regularities have been found. A new parameter δ12 indicating the interaction energy between unlike molecules has been defined and discussed. The extension of Scatchard-Hildebrand equation from binary systems to multicomponent systems with metal complexes in organic phase (EHEHPA-nC7H16-CoSO4-CuSO4 extraction system) is also studied. The real “thermodynamic equilibrium constants” for metal extraction reactions have been determined." @default.
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- W2085361503 date "1986-01-01" @default.
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- W2085361503 title "A study of scatchard-hildebrand solution theory for metal solvent extraction systems" @default.
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- W2085361503 doi "https://doi.org/10.1016/0378-3812(86)80063-2" @default.
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