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- W2085363903 abstract "The electron beam induced reduction of Cu(II) oxide has been studied by means of XPS and HREELS. The Cu(II) ions are reduced to Cu(I) within a limited surface layer. The effectiveness of the reduction strongly depends on the presence of a surface carbonaceous layer. The possible mechanism for reduction may be the breaking of C-H bonds and the interaction of the created hydrocarbon species with the surface oxygen. Due to this mechanism only the surface layer of copper oxide is reduced. Applying XPS and HREELS techniques it is possible to derive information about the distribution of copper cations as a function of depth. The method described here can be applied for studying the reducibility of other oxide systems without altering their bulk composition." @default.
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- W2085363903 date "1989-04-01" @default.
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- W2085363903 title "Electron beam induced reduction of CuO in the presence of a surface carbonaceous layer: an XPS/HREELS study" @default.
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- W2085363903 doi "https://doi.org/10.1016/0039-6028(89)90313-0" @default.
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