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- W2085367192 abstract "The electron transfer reaction trioxalatoferriate/trioxalatoferrate was measured on the dropping mercury electrode by the galvanostatic double-pulse method using an improved controlled-current double-pulse supply. The apparent standard rate constant and the transfer coefficient were obtained as 1.44±0.05 cm s−1 and 0.85±0.05, respectively, at 25°C. These are in fairly good agreement with the corresponding values obtained by De Leeuwe et al. with the faradaic rectification method: 1.16±0.04 cm s−1 and 0.86±0.04. These two methods of measurement can give consistent results in the measurement of the kinetic parameters of fast electrode reactions with high rate constants approaching the upper limit accessible with existing methods. The area of the dropping mercury electrode was adjusted to have a definite value at the moment of application of the double-pulse. A simple set-up to detect the drop fall was arranged for this purpose." @default.
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- W2085367192 date "1972-07-01" @default.
- W2085367192 modified "2023-09-26" @default.
- W2085367192 title "Kinetic parameters of trioxalatoferriate/trioxalatoferrate electrode reaction measured by the galvanostatic double-pulse method" @default.
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- W2085367192 doi "https://doi.org/10.1016/s0022-0728(72)80088-3" @default.
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